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Electrochemical determination of epinine by using modified Screen-Printed electrode | ||
| Iranian Journal of Analytical Chemistry | ||
| دوره 11، شماره 2 - شماره پیاپی 22، آذر 2024، صفحه 223-229 اصل مقاله (676.98 K) | ||
| نوع مقاله: Full research article | ||
| شناسه دیجیتال (DOI): 10.30473/ijac.2026.77132.1337 | ||
| نویسندگان | ||
| Sayed Zia Mohammadi* 1؛ Elina Baniassadi2؛ Somayeh Tajik3 | ||
| 1Payame Noor University, Kerman, Iran | ||
| 21Department of Chemistry, Payame Noor University, Tehran, Iran | ||
| 32Research Center of Tropical and Infectious Diseases, Kerman University of Medical Sciences, P.O. Box 76169 13555, Kerman, Iran | ||
| چکیده | ||
| In the present work, we designed a disposable voltammetric sensor utilizing a manganese ferrite nanoparticles -modified screen-printed electrode (MF/SPE) for epinine determination. The electrochemical behavior of EP at the MF/SPE was examined using differential pulse voltammetry (DPV), cyclic voltammetry (CV), and chronoamperometry techniques. The MF/SPE exhibited outstanding electro-catalytic activity for the voltammetric detection of EP. Under optimized conditions, the peak current showed a linear dependence with the concentration of EP in the range of 0.1 to 600.0 µM, and a detection limit (LOD) of 0.02 µM was determined. In addition, the MF/SPE sensor has advantages including repeatability, reproducibility, stability, inexpensiveness, and practical application. Finally, the MF/SPE -based sensor was utilized for the determination of EP in the real urine samples and the satisfactory results were obtained. | ||
| کلیدواژهها | ||
| disposable sensor؛ manganese ferrite nanoparticles؛ electrochemical sensor؛ Epinie | ||
| عنوان مقاله [English] | ||
| تعیین الکترو شیمیایی اپینین با استفاده از الکترود صفحه چاپی اصلاح شده | ||
| نویسندگان [English] | ||
| سید ضیا محمدی1؛ | ||
| 1دانشگاه پیام نور مرکز کرمان | ||
| چکیده [English] | ||
| در کار حاضر، یک حسگر ولتامتری یکبار مصرف با استفاده از الکترود صفحه چاپی اصلاح شده با نانوذرات فریت منگنز (MF/SPE) برای تعیین اپینین(EP) طراحی گردید. رفتار الکتروشیمیایی EP در سطح MF/SPEبا استفاده از تکنیکهای ولتامتری پالس تفاضلی (DPV)، ولتامتری چرخهای (CV) و کرونوآمپرومتری بررسی شد. الکنرود MF/SPE فعالیت الکتروکاتالیستی برجستهای را برای تعیین ولتامتری EP نشان داد. تحت شرایط بهینه، جریان پیک وابستگی خطی با غلظت EP در محدوده 1/0 تا0/600 میکرومولار نشان داد و حد تشخیص (LOD) 02/0 میکرومولار تعیین شد. علاوه بر این، حسگر MF/SPE مزایایی از جمله تکرارپذیری، تکثیرپذیری، پایداری، ارزان بودن و قابلت کاربردهای عملی را دارد. در پایان، حسگر مبتنی بر MF/SPE برای تعیین EP در نمونههای ادرار مورد استفاده قرار گرقت و نتایج رضایت بخشی بدست آمد. | ||
| کلیدواژهها [English] | ||
| حسگر یکبار مصرف, نانوذرات فریت منگنز, حسگر الکتروشیمیایی, اپینین | ||
| مراجع | ||
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آمار تعداد مشاهده مقاله: 31 تعداد دریافت فایل اصل مقاله: 20 |
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