Abedi, Reza, Parchehbaf Jadid, Aiyoub, Azari, Zhila. (1401). Modified Sodium Dodecyl Sulfate Coated γ-Alumina Nanoparticles with (e)n'-(2-Hydroxybenzylidene)Isonicotinohydrazide as New Sorbent for Copper Determination in Real Samples. فصلنامه علمی زیست فناوری گیاهان زراعی, 9(2), 10-18. doi: 10.30473/ijac.2022.63578.1231
Reza Abedi; Aiyoub Parchehbaf Jadid; Zhila Azari. "Modified Sodium Dodecyl Sulfate Coated γ-Alumina Nanoparticles with (e)n'-(2-Hydroxybenzylidene)Isonicotinohydrazide as New Sorbent for Copper Determination in Real Samples". فصلنامه علمی زیست فناوری گیاهان زراعی, 9, 2, 1401, 10-18. doi: 10.30473/ijac.2022.63578.1231
Abedi, Reza, Parchehbaf Jadid, Aiyoub, Azari, Zhila. (1401). 'Modified Sodium Dodecyl Sulfate Coated γ-Alumina Nanoparticles with (e)n'-(2-Hydroxybenzylidene)Isonicotinohydrazide as New Sorbent for Copper Determination in Real Samples', فصلنامه علمی زیست فناوری گیاهان زراعی, 9(2), pp. 10-18. doi: 10.30473/ijac.2022.63578.1231
Abedi, Reza, Parchehbaf Jadid, Aiyoub, Azari, Zhila. Modified Sodium Dodecyl Sulfate Coated γ-Alumina Nanoparticles with (e)n'-(2-Hydroxybenzylidene)Isonicotinohydrazide as New Sorbent for Copper Determination in Real Samples. فصلنامه علمی زیست فناوری گیاهان زراعی, 1401; 9(2): 10-18. doi: 10.30473/ijac.2022.63578.1231
1Department of Chemistry, Payame Noor University, P. O. Box 19395-3697, Tehran, Iran
2Department of Applied Chemistry, Ardabil Branch, Islamic Azad University, Ardabil, Iran
چکیده
In this study, a novel and efficient solid phase extraction method based on the use of γ-alumina (γ-Al2O3) nanoparticles coated with sodium dodecyl sulfate and modified with (E)N'-(2-hydroxy benzylidene) isonicotinohydrazide (H2L) as a new adsorbent was developed for separation and determination of trace amounts of copper(II) prior to flame atomic absorption spectrometry (FAAS). The analyte ions were adsorbed quantitatively on adsorbent due to their complexation with (H2L). The separation procedure was studied with regard to experimental parameters such as pH, amount of sodium dodecyl sulfate , ligand’s concentration, contact time, type and volume of eluent and stirring rate. The effects of interfering ions on the extraction procedure were also investigated. Under the optimum experimental conditions, the extraction efficiency was 98, 97 and 95.5 with relative standard deviation lower than 5% for Shurabil Lake, the collected water behind the barrier and Baligluchai River, respectively. Noticeably, the method has been successfully applied for the extraction and determination of copper content in some real samples.
اصلاح نانو ذرات گاما آلومینای پوشش داده‌شده از سدیم دو دسیل سولفات با لیگاند H2L به عنوان جاذب جدید برای اندازه‌گیری مس در نمونه‌های واقعی
نویسندگان [English]
رضا عابدی1؛ ایوب پارچه باف جدید2؛ ژیلا آذری1
1گروه شیمی، دانشگاه پیام نور، تهران، ایران
2گروه شیمی، دانشگاه آزاد اسلامی، واحد اردبیل، اردبیل، ایران
چکیده [English]
چکیده
دراین مطالعه، یک روش جدید وکارآمد استخراج فازجامد، مبتنی براصلاح نانوذرات گاما آلومینای پوشش داده شده با سدیم دودسیل سولفات با لیگاند H2L به عنوان یک جاذب جدید برای جداسازی و اندازه گیری مقادیرکمی مس (II) توسط طیف سنجی جذب اتمی شعله ای توسعه داده شده است. یونهای آنالیت به دلیل کمپلکسشدن با لیگاند به صورت کمی روی جاذب جذب و فرآیند جداسازی به وسیله پارامترهای موثر مانندpH، مقدار سدیم دودسیل سولفات، غلظت لیگاند، زمان تماس، نوع و حجم شوینده و سرعت همزدن مورد بررسی قرارگرفته اند. اثرات یون های مزاحم برروی روش استخراج نیز بررسی و بهینه شدند. تحت شرایط بهینه راندمان استخراج 98، 97 و 95.5 با انحراف معیار نسبی کمتر از5 درصد برای دریاچه شورابیل، آب جمع‌آوری‌شده پشت سد و رودخانه بالیقلوچای به دست آمد. قابل توجه است که این روش با موفقیت برای استخراج و اندازه‌گیری مس دربرخی از نمونه های واقعی استفاده شد.
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