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Pourhakkak, Parvin, Karimi, Mohammad Ali, Tavallali, Hossein, Pourhakkak, Pouran, Mazloum Ardakani, Mohammad. (1401). A New Potentiometric Sensor for Rapid Determination of Captopril in Pharmaceutical Formulation and Biological Samples. فصلنامه علمی زیست فناوری گیاهان زراعی, 9(2), 19-27. doi: 10.30473/ijac.2022.63786.1234
Parvin Pourhakkak; Mohammad Ali Karimi; Hossein Tavallali; Pouran Pourhakkak; Mohammad Mazloum Ardakani. "A New Potentiometric Sensor for Rapid Determination of Captopril in Pharmaceutical Formulation and Biological Samples". فصلنامه علمی زیست فناوری گیاهان زراعی, 9, 2, 1401, 19-27. doi: 10.30473/ijac.2022.63786.1234
Pourhakkak, Parvin, Karimi, Mohammad Ali, Tavallali, Hossein, Pourhakkak, Pouran, Mazloum Ardakani, Mohammad. (1401). 'A New Potentiometric Sensor for Rapid Determination of Captopril in Pharmaceutical Formulation and Biological Samples', فصلنامه علمی زیست فناوری گیاهان زراعی, 9(2), pp. 19-27. doi: 10.30473/ijac.2022.63786.1234
Pourhakkak, Parvin, Karimi, Mohammad Ali, Tavallali, Hossein, Pourhakkak, Pouran, Mazloum Ardakani, Mohammad. A New Potentiometric Sensor for Rapid Determination of Captopril in Pharmaceutical Formulation and Biological Samples. فصلنامه علمی زیست فناوری گیاهان زراعی, 1401; 9(2): 19-27. doi: 10.30473/ijac.2022.63786.1234

A New Potentiometric Sensor for Rapid Determination of Captopril in Pharmaceutical Formulation and Biological Samples

Iranian Journal of Analytical Chemistry
دوره 9، شماره 2 - شماره پیاپی 18، آذر 2022، صفحه 19-27    اصل مقاله (845.83 K)
نوع مقاله: Full research article
شناسه دیجیتال (DOI): 10.30473/ijac.2022.63786.1234
نویسندگان
Parvin Pourhakkak1؛ Mohammad Ali Karimi* 1؛ Hossein Tavallali1؛ Pouran Pourhakkak1؛ Mohammad Mazloum Ardakani2
1Department of Chemistry, Payame Noor University, Tehran, Iran
2Department of Chemistry, Faculty of Science, Yazd University, Yazd, 89195-741, Iran
چکیده
A new potentiometric sensor based on a β- cyclodextrin modified carbon paste electrode (CPE) was designed for the determination of the captopril drug. The effect of various cyclodextrins (α, β and γ- cyclodextrins) and their percentage, binder agent and ion additive on the potential response have been investigated and the electrode with the best potential response was found. The linear concentration range for this electrode was 7.0×10-7-1.0×10-1 M with a low detection limit of 2.0 × 10-7 M. The effect of pH and temperature on the Nernstian slope was also investigated and the optimal range was obtained. The selectivity of the captopril CPE to interfering species including Li+, K+, Ni+, Mg2+, Ca2+, Co2+, Cr2+, Cr3+, Zn2+,Mn2+, Fe2+, F-, Cl-, SO42-, C2O42- PO43-, C2O42-, ascorbic acid, uric acid, glucose, D-fructose and sucrose was determined by Separate Solution (SSM) and Matched Potential Method (MPM) methods. Finally, the proposed electrode was tested for measuring captopril in drug formulation, blood serum, and urine samples. 
کلیدواژه‌ها
Potentiometric Sensor؛ Captopril؛ Modified Carbon Paste Electrode؛ β-Cyclodextrin؛ Ion-Selective Electrode
عنوان مقاله [English]
یک حسگر پتانسیومتری جدید برای اندازه گیری سریع کاپتوپریل در فرمولاسیون دارویی و نمونه های بیولوژیکی
نویسندگان [English]
پروین پورحکاک1؛ محمدعلی کریمی1؛ حسین توللی1؛ پوران پورحکاک1؛ محمد مظلوم اردکانی2
1گروه شیمی، دانشگاه پیام نور، تهران، ایران
2گروه شیمی، دانشکده علوم، دانشگاه یزد، یزد، ایران
چکیده [English]
یک حسگر پتانسیومتری جدید بر اساس یک الکترود خمیر کربن (CPE) اصلاح شده β- سیکلودکسترین برای اندازه گیری داروی کاپتوپریل طراحی شده است. اثر سیکلودکسترین های مختلف (سیکلودکسترین های α، β و γ-) و درصد آنها، عامل چسبنده و افزودنی یونی بر پاسخ پتانسیل بررسی شده و الکترودی با بهترین پاسخ پتانسیل به دست آمد. محدوده غلظت خطی برای این الکترود 7- 10 × 7.0 - 1- 10 × 1.0 مولار با حد تشخیص پایین 7- 10 × 2.0 مولار بود. تأثیر pH و دما بر شیب نرنستی نیز بررسی شد و محدوده بهینه به دست آمد. گزینش پذیری captopril CPE به گونه های مزاحم شامل Li+، K+، Ni+، Mg2+، Ca2+، Co2+، Cr2+، Cr3+، Zn2+، Mn2+، Fe2+، F-، Cl-، SO42-، C2O42- PO43-، C2O42-، آسکوربیک اسید، اوریک اسید، گلوکز، D-فروکتوز و ساکارز با روش‌ محلول جداگانه (SSM) و روش پتانسیل همسان (MPM) تعیین شد. در نهایت، الکترود پیشنهادی برای اندازه‌گیری کاپتوپریل در فرمولاسیون دارو، سرم خون و نمونه‌های ادرار مورد آزمایش قرار گرفت.
کلیدواژه‌ها [English]
حسگر پتانسیومتری, کاپتوپریل, β-سیکلودکسترین, الکترود خمیر کربن اصلاح شده, الکترود انتخابگر یونی
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