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Azizkhani, Vahid, Ramazani, Ali, Woo Joo, Sang. (1394). Ammonium nitrate as an efficient and green reagent for the oxidation of alcohols into their corresponding carbonyl compounds in the presence of heteropoly acids. فصلنامه علمی زیست فناوری گیاهان زراعی, 3(Issue 2, pp. 72-147, Serial No. 7), 121-131.
Vahid Azizkhani; Ali Ramazani; Sang Woo Joo. "Ammonium nitrate as an efficient and green reagent for the oxidation of alcohols into their corresponding carbonyl compounds in the presence of heteropoly acids". فصلنامه علمی زیست فناوری گیاهان زراعی, 3, Issue 2, pp. 72-147, Serial No. 7, 1394, 121-131.
Azizkhani, Vahid, Ramazani, Ali, Woo Joo, Sang. (1394). 'Ammonium nitrate as an efficient and green reagent for the oxidation of alcohols into their corresponding carbonyl compounds in the presence of heteropoly acids', فصلنامه علمی زیست فناوری گیاهان زراعی, 3(Issue 2, pp. 72-147, Serial No. 7), pp. 121-131.
Azizkhani, Vahid, Ramazani, Ali, Woo Joo, Sang. Ammonium nitrate as an efficient and green reagent for the oxidation of alcohols into their corresponding carbonyl compounds in the presence of heteropoly acids. فصلنامه علمی زیست فناوری گیاهان زراعی, 1394; 3(Issue 2, pp. 72-147, Serial No. 7): 121-131.

Ammonium nitrate as an efficient and green reagent for the oxidation of alcohols into their corresponding carbonyl compounds in the presence of heteropoly acids

Iranian chemical communication
مقاله 7، دوره 3، Issue 2, pp. 72-147, Serial No. 7، تیر 2015، صفحه 121-131    اصل مقاله (782.04 K)
نوع مقاله: Original Research Article
نویسندگان
Vahid Azizkhani1؛ Ali Ramazani* 2؛ Sang Woo Joo3
1Unuversity of Zanjan
2University of Zanjan
3Yeungnam University
چکیده
Simple, cheap and green protocol for effective conversion of alcohols to corresponding carbonyl compounds in the presence of H14[NaP5W30O110] and ammonium nitrate is reported. The products were characterized by FT-IR and comparison of their physical properties with those reported in the literatures. The progress of the reaction was monitored by thin layer chromatography (TLC) technique. The aliphatic products were detected by gas chromatography–flame ionization detector. Reactions were completed within 15-35 minutes at room temperature. In order to investigate the catalyst reusability, the oxidation of benzyl alcohol was carried out in the presence of H14[NaP5W30O110]. At the end of each reaction, the catalyst was separated and the recovered catalyst was reused for at least three runs without significant degradation in catalytic activity and performance.
کلیدواژه‌ها
alcohols؛ heteropoly acids؛ Oxidation؛ Heterogeneous catalyst؛ ammonium nitrate؛ energetic materials
مراجع

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