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Zare, Abdolkarim, Rezaei, Mahshad, Hasaninejad, Alireza. (1394). 1,3-Disulfonic acid imidazolium hydrogen sulfate {[Dsim]HSO4} as a highly efficient, recyclable and green catalyst for the preparation of α,α´-bis(arylidene)cycloalkanones. فصلنامه علمی زیست فناوری گیاهان زراعی, 4(Issue 1, pp. 1-132, Serial No. 10), 94-101.
Abdolkarim Zare; Mahshad Rezaei; Alireza Hasaninejad. "1,3-Disulfonic acid imidazolium hydrogen sulfate {[Dsim]HSO4} as a highly efficient, recyclable and green catalyst for the preparation of α,α´-bis(arylidene)cycloalkanones". فصلنامه علمی زیست فناوری گیاهان زراعی, 4, Issue 1, pp. 1-132, Serial No. 10, 1394, 94-101.
Zare, Abdolkarim, Rezaei, Mahshad, Hasaninejad, Alireza. (1394). '1,3-Disulfonic acid imidazolium hydrogen sulfate {[Dsim]HSO4} as a highly efficient, recyclable and green catalyst for the preparation of α,α´-bis(arylidene)cycloalkanones', فصلنامه علمی زیست فناوری گیاهان زراعی, 4(Issue 1, pp. 1-132, Serial No. 10), pp. 94-101.
Zare, Abdolkarim, Rezaei, Mahshad, Hasaninejad, Alireza. 1,3-Disulfonic acid imidazolium hydrogen sulfate {[Dsim]HSO4} as a highly efficient, recyclable and green catalyst for the preparation of α,α´-bis(arylidene)cycloalkanones. فصلنامه علمی زیست فناوری گیاهان زراعی, 1394; 4(Issue 1, pp. 1-132, Serial No. 10): 94-101.

1,3-Disulfonic acid imidazolium hydrogen sulfate {[Dsim]HSO4} as a highly efficient, recyclable and green catalyst for the preparation of α,α´-bis(arylidene)cycloalkanones

Iranian chemical communication
مقاله 8، دوره 4، Issue 1, pp. 1-132, Serial No. 10، فروردین 2016، صفحه 94-101    اصل مقاله (116.12 K)
نوع مقاله: Original Research Article
نویسندگان
Abdolkarim Zare* 1؛ Mahshad Rezaei2؛ Alireza Hasaninejad3
1Department of Chemistry, Payame Noor University of Bushehr, Bushehr, Iran
2Department of Chemistry, Payame Noor University, Tehran, P.O. Box 19395-4697, Iran
3Department of Chemistry, Faculty of Sciences, Persian Gulf University, Bushehr 75169, Iran
چکیده
A highly efficient and simple method for the preparation of α,α´-bis(arylidene)cycloalkanones under solvent-free conditions has been developed. The crossed-aldol condensation of cycloalkanones (1 eq.) with arylaldehydes (2 eq.) in the presence of 2.5 mol% of ionic liquid 1,3-disulfonic acid imidazolium hydrogen sulfate {[Dsim]HSO4} afforded the title compounds in high yields and short reaction times. The catalyst has dual-functions and it is so because of possessing three acidic functional groups with different Brønsted acidic and basic sites. High catalytic activity and low loading of the catalyst can be attributed to its dual-functions. The promising points for the presented protocol are simple and clean reaction profile, efficiency, generality, low catalyst loading, high yields, performing the reaction in solvent-free media without side reactions, non-toxicity as well as low cost of the catalyst, and good compliance with the green chemistry protocols, which makes it an attractive procedure for the synthesis of α,α´-bis(arylidene)cycloalkanones as an important class of organic compounds.
کلیدواژه‌ها
α؛ α´-Bis(arylidene)cycloalkanone؛ 1؛ 3-disulfonic acid imidazolium hydrogen sulfate {[Dsim]HSO4}؛ acidic ionic liquid؛ crossed-aldol condensation
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