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Ershad, Sohrab, Safarzadeh, Noshin, Akhondi-Yamchi, Hamzeh. (1395). Application of carbon ceramic modified electrode with prussian blue for electrocatalytic oxidation of nitrite ion. فصلنامه علمی زیست فناوری گیاهان زراعی, 4(Issue 3, pp. 236-358, Serial No. 12), 256-264.
Sohrab Ershad; Noshin Safarzadeh; Hamzeh Akhondi-Yamchi. "Application of carbon ceramic modified electrode with prussian blue for electrocatalytic oxidation of nitrite ion". فصلنامه علمی زیست فناوری گیاهان زراعی, 4, Issue 3, pp. 236-358, Serial No. 12, 1395, 256-264.
Ershad, Sohrab, Safarzadeh, Noshin, Akhondi-Yamchi, Hamzeh. (1395). 'Application of carbon ceramic modified electrode with prussian blue for electrocatalytic oxidation of nitrite ion', فصلنامه علمی زیست فناوری گیاهان زراعی, 4(Issue 3, pp. 236-358, Serial No. 12), pp. 256-264.
Ershad, Sohrab, Safarzadeh, Noshin, Akhondi-Yamchi, Hamzeh. Application of carbon ceramic modified electrode with prussian blue for electrocatalytic oxidation of nitrite ion. فصلنامه علمی زیست فناوری گیاهان زراعی, 1395; 4(Issue 3, pp. 236-358, Serial No. 12): 256-264.

Application of carbon ceramic modified electrode with prussian blue for electrocatalytic oxidation of nitrite ion

Iranian chemical communication
مقاله 15، دوره 4، Issue 3, pp. 236-358, Serial No. 12، مهر 2016، صفحه 256-264    اصل مقاله (593.32 K)
نوع مقاله: Original Research Article
نویسندگان
Sohrab Ershad* 1؛ Noshin Safarzadeh2؛ Hamzeh Akhondi-Yamchi2
1marand
2Department of Chemistry, Payame Noor University, P.O. BOX 19395-4697 Tehran, Iran
چکیده
A novel chemically modified electrode containing Prussian blue complex was achieved on the surface of glass carbon electrode by sol-gel technique. The electrochemical behavior of modified electrode was characterized by cyclic voltammetry in detail. The film electrode obtained was very stable and exhibited electrocatalytic response for oxidation of nitrite. Results showed at bare GC electrode, a small oxidation peak current was observed at about 740 mV and a well-formed sharp catalytic oxidation peak at about 600 mV was observed at Prussian blue complex modified electrode. The transfer coefficient (α) for electrocatalytic oxidation of nitrite and the diffusion coefficient of this substance under the experimental conditions were also investigated.
کلیدواژه‌ها
Prussian blue complex؛ cyclic voltammetry؛ nitrite؛ electrocatalytic oxidation
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