An efficient green synthesis of highly substituted imidazoles catalyzed by Al-MCM-41 nanoreactors

Olyaei, Abolfazl; Derikvand, Zohreh; Noruzian, Fatemeh; Sadeghpour, Mahdieh

- فلوچارت مراحل ورود و ثبت نام در سامانه نشریات علمی وزارت عتف

- راه اندازی سیستم مدیریت نشریات علمی دانشگاه پیام نور

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	An efficient green synthesis of highly substituted imidazoles catalyzed by Al-MCM-41 nanoreactors
Iranian chemical communication
مقاله 23، دوره 4، Issue 3, pp. 236-358, Serial No. 12، مهر 2016، صفحه 337-346 اصل مقاله (145.65 K)
نوع مقاله: Original Research Article
نویسندگان
Abolfazl Olyaei^* ¹؛ Zohreh Derikvand²؛ Fatemeh Noruzian³؛ Mahdieh Sadeghpour⁴
¹Department of Chemistry, Payame Noor University, Qazvin, Iran
²bDepartment of Chemistry, Faculty of Science, Khorramabad Branch, Islamic Azad University, Khorramabad, Iran
³Department of Chemistry, Payame Noor University, PO BOX 19395-3697, Tehran, I. R. of Iran Tel.: 0098-28-33224024; Fax number: 0098-28-33226400
⁴Department of Chemistry, Takestan Branch, Islamic Azad University, Takestan, Iran
چکیده
Al-MCM-41 nanoreactors is found to be a remarkable efficient catalyst for one-pot multicomponent cyclocondensation of benzil, aniline or ammonium acetate and aromatic aldehydes for the synthesis of polysubstituted imidazoles under solvent-free conditions. The reaction was efficiently promoted by 10 mg nano-Al-MCM-41 and the heterogeneous catalyst was recycled for four runs in this reaction without losing its catalytic activity. The key advantages of this process are operational simplicity, reusable catalyst, shorter reaction time, convenient work-up procedures, avoiding the use of organic solvents and purification of products by non-chromatographic methods. By this advantage, several polysubstituted imidazoles as pharmaceutical important molecules can be prepared in high yield and high purity.
کلیدواژه‌ها
Nano-Al-MCM-41؛ aromatic aldehyde؛ benzil؛ imidazole؛ aniline

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An efficient green synthesis of highly substituted imidazoles catalyzed by Al-MCM-41 nanoreactors

[3] A. Puratchikody, Bioorg. Med. Chem. Lett., 2007, 15, 1083-1085.

[4] J. Safari, Monatsh. Chem., 2010, 141, 1339-1345.

[10] A. Shaabani, A. Rahmati, J. Mol. Catal. A: Chem., 2006, 249, 246-248.

[11] (a) S.D. Sharma, P. Hazarika, D. Konwar, Tetrahedron Lett., 2008, 49, 2216-2220; (b) J.N. Sangshetti, N.D. Kokare, S.A. Kothrkara, D.B. Shinde, J. Chem. Sci., 2008, 120, 463-467; (c) M.M. Heravi, K. Bakhtiari, H.A. Oskooie, S. Taheri, J. Mol. Catal. A: Chem., 2007, 263, 279-281.

[14] B. Sadeghi, B.B.F. Mirjalili, M.M. Hashemi, Tetrahedron Lett., 2008, 49, 2575-2577.

[19] R. Hekmat Shoar, G. Rahimzadeh, F. Derikvand, M. Farzaneh, Synth. Commun., 2010, 40, 1270-1275.

[20] M. Kidwai, P. Mothsra, V. Bansal, R.K. Somvanshi, A.S. Ethayathulla, S. Dey, T.P. Singh, J. Mol. Catal. A: Chem., 2007, 265, 177-182.

[23] S.A. Dake, M.B. Khedkar, G.S. Irmale, S.J. Ukalgaonkar, V.V. Thorat, S.A. Shintre, R.P. Pawar, Synth. Commun., 2012, 42, 1509-1529.

[25] K. Niknam, A. Deris, F. Naeimi, F. Majleci, Tetrahedron Lett., 2011, 52, 642-4645.

[29] G. Nagalakshmi, E-Journal Chem., 2008, 5, 447-452.

[30] V. Kannan, K. Sreekumar. J. Mol. Catal. A: Chem., 2013, 376, 34-39.

[36] P. Gayathri, A. Thiruvalluvar, N. Srinivasan, J. Jayabharathi R.J. Butcher, Acta Cryst., 2010, E66, o2519.