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Application of the extended solvation theory to study the interaction of β-CD with interpolymer of PEO and PAA | ||
| Iranian chemical communication | ||
| مقاله 7، دوره 5، Issue 3, pp. 237-363, Serial No. 16، مهر 2017، صفحه 286-292 اصل مقاله (833.01 K) | ||
| نوع مقاله: Original Research Article | ||
| نویسندگان | ||
| Bahman Vasheghani Farahani* 1؛ Golamreza Rezaei Behbahani2؛ Monir Shalbafan2 | ||
| 1IMMAM KHOMEINI INTERNATHIONAL UNIVERSITY | ||
| 2Imam Khomeini International University | ||
| چکیده | ||
| Thermodynamic study on the interaction of β-CD with poly ethylene oxide and poly acrylic acid was performed by isothermal titration calorimetry at 298K. when β-CD is added to the interpolymer complex, competition is created between host-guest and Hydrogen bond. Enthalpy of interaction between the β-CD and interpolymer complex was calculated using the extended solvation theory. P=1 Shows that willingness of β-CD to interact with both polymers is identical. The positive values of and show that interpolymer complex are stabilized by β-CD . The process is both enthalpy and entropy-driven. The results show that this interaction is exothermic and increases the interpolymer complex stability. | ||
| کلیدواژهها | ||
| β-CD؛ poly ethylene oxide؛ poly acrylic acid؛ isothermal titration calorimetry | ||
| مراجع | ||
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