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Noroozi Pesyan, Nader, Gholsanamloo, Vali, Moradi Par, Maryam, Rashidnejad, Hamid, Gharib, Ali, Nejati, Kamelia. (1397). Synthesis, characterization and spectroscopic properties of new azo dyes derived from aniline derivatives based on acetylacetone and azo-metal (II) complexes and singular value decomposition (SVD) investigation. فصلنامه علمی زیست فناوری گیاهان زراعی, 7(Issue 1, pp. 1-89, Serial No. 22), 71-89. doi: 10.30473/icc.2019.3951
Nader Noroozi Pesyan; Vali Gholsanamloo; Maryam Moradi Par; Hamid Rashidnejad; Ali Gharib; Kamelia Nejati. "Synthesis, characterization and spectroscopic properties of new azo dyes derived from aniline derivatives based on acetylacetone and azo-metal (II) complexes and singular value decomposition (SVD) investigation". فصلنامه علمی زیست فناوری گیاهان زراعی, 7, Issue 1, pp. 1-89, Serial No. 22, 1397, 71-89. doi: 10.30473/icc.2019.3951
Noroozi Pesyan, Nader, Gholsanamloo, Vali, Moradi Par, Maryam, Rashidnejad, Hamid, Gharib, Ali, Nejati, Kamelia. (1397). 'Synthesis, characterization and spectroscopic properties of new azo dyes derived from aniline derivatives based on acetylacetone and azo-metal (II) complexes and singular value decomposition (SVD) investigation', فصلنامه علمی زیست فناوری گیاهان زراعی, 7(Issue 1, pp. 1-89, Serial No. 22), pp. 71-89. doi: 10.30473/icc.2019.3951
Noroozi Pesyan, Nader, Gholsanamloo, Vali, Moradi Par, Maryam, Rashidnejad, Hamid, Gharib, Ali, Nejati, Kamelia. Synthesis, characterization and spectroscopic properties of new azo dyes derived from aniline derivatives based on acetylacetone and azo-metal (II) complexes and singular value decomposition (SVD) investigation. فصلنامه علمی زیست فناوری گیاهان زراعی, 1397; 7(Issue 1, pp. 1-89, Serial No. 22): 71-89. doi: 10.30473/icc.2019.3951

Synthesis, characterization and spectroscopic properties of new azo dyes derived from aniline derivatives based on acetylacetone and azo-metal (II) complexes and singular value decomposition (SVD) investigation

Iranian chemical communication
مقاله 7، دوره 7، Issue 1, pp. 1-89, Serial No. 22، فروردین 2019، صفحه 71-89    اصل مقاله (1.64 M)
نوع مقاله: Original Research Article
شناسه دیجیتال (DOI): 10.30473/icc.2019.3951
نویسندگان
Nader Noroozi Pesyan* 1؛ Vali Gholsanamloo2؛ Maryam Moradi Par2؛ Hamid Rashidnejad2؛ Ali Gharib3؛ Kamelia Nejati4
1Faculty of Chemistry, Urmia University, 57159, Urmia, Iran
2Faculty of Chemistry, Urmia University, 57159,Urmia, Iran
3Department of Chemistry, Islamic Azad University, Mashhad, Iran
4Department of Chemistry, Payame Noor University, PO.BOX 19395-3697 Tehran, Iran
چکیده
Four new azo-dyes, 3-phenyl azopentane-2,4-dion (LA), 3-(4-nitro phenyl azo)-pentane-2,4-dion (LP), 3-(2-nitro phenyl azo)-pentane-2,4-dion (LO) and 4-(1-acetyle-2-oxo-propyl azo)-benzene sulfonate sodium (LS), were synthesized from, aniline, 4-nitroaniline, 2-nitroaniline and sulfanilic acid with acetylacetone, respectively. Reaction of these new dyes with acetate salts of copper(II), nickel(II) and cobalt(II) in molar ratios of 1:2 were carried out to produce azo metal (II) complexes with the general stoichiometry; CuL2, CoL2 and NiL3 in complexes. Structure of azo dyes was characterized using FT-IR,1H NMR,13C NMR, UV-Visible and also the corresponding metal (II) complex were characterized by FT IR, UV-Visible and CHN and XRD analysis techniques. Elemental analysis and spectral data indicated that the dye as a ligand with two teeth, N and O, acts as a bidentate ligand. Differences in absorption maxima of azo ligands compared to those corresponding complexes were also studied. Also, in this work, singular value decomposition (SVD) as a chemometric method was used to determine the Cu(II), Co(II) and Ni(II) complexes with the mentioned ligands in methanol by UV-Vis spectrophotometry. SVD method confirmed the formation of CuL2, CoL2 and NiL3 complexes.
کلیدواژه‌ها
azo dye؛ sulfanilic acid؛ acetylacetone؛ bifurcated intramolecular H-bond؛ azo-metal (II) complex
مراجع
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