اخبار و اعلانات

 آمار

تعداد نشریات41
تعداد شماره‌ها1,138
تعداد مقالات9,757
تعداد مشاهده مقاله17,845,301
تعداد دریافت فایل اصل مقاله12,462,926
Oftadeh, Mohsen, Hajati, Fahad, Jamshidi, Mortaza, Javaherian Naghash, Hamid. (1397). Study of structure and thermal properties of styrene-butylacrylate ‎copolymer with OMMT nanocomposite emulsions. فصلنامه علمی زیست فناوری گیاهان زراعی, 7(Issue 1, pp. 1-89, Serial No. 22), 63-70. doi: 10.30473/icc.2019.4234
Mohsen Oftadeh; Fahad Hajati; Mortaza Jamshidi; Hamid Javaherian Naghash. "Study of structure and thermal properties of styrene-butylacrylate ‎copolymer with OMMT nanocomposite emulsions". فصلنامه علمی زیست فناوری گیاهان زراعی, 7, Issue 1, pp. 1-89, Serial No. 22, 1397, 63-70. doi: 10.30473/icc.2019.4234
Oftadeh, Mohsen, Hajati, Fahad, Jamshidi, Mortaza, Javaherian Naghash, Hamid. (1397). 'Study of structure and thermal properties of styrene-butylacrylate ‎copolymer with OMMT nanocomposite emulsions', فصلنامه علمی زیست فناوری گیاهان زراعی, 7(Issue 1, pp. 1-89, Serial No. 22), pp. 63-70. doi: 10.30473/icc.2019.4234
Oftadeh, Mohsen, Hajati, Fahad, Jamshidi, Mortaza, Javaherian Naghash, Hamid. Study of structure and thermal properties of styrene-butylacrylate ‎copolymer with OMMT nanocomposite emulsions. فصلنامه علمی زیست فناوری گیاهان زراعی, 1397; 7(Issue 1, pp. 1-89, Serial No. 22): 63-70. doi: 10.30473/icc.2019.4234

Study of structure and thermal properties of styrene-butylacrylate ‎copolymer with OMMT nanocomposite emulsions

Iranian chemical communication
مقاله 6، دوره 7، Issue 1, pp. 1-89, Serial No. 22، فروردین 2019، صفحه 63-70    اصل مقاله (992.17 K)
نوع مقاله: Original Research Article
شناسه دیجیتال (DOI): 10.30473/icc.2019.4234
نویسندگان
Mohsen Oftadeh* 1؛ Fahad Hajati2؛ Mortaza Jamshidi2؛ Hamid Javaherian Naghash2
1Chemistry Department, Payame Noor University, 19395-4697 Tehran, Iran
2Department of Chemistry, Islamic Azad University, Shahreza Branch, P.O.BOX 311-86145, Shahreza, Isfahan, Iran.
چکیده
‎(St-co-BA) polymer through montmorillonite (MMT) nanocomposite emulsion is prepared by ‎in situ intercalative emulsion polymerization of styrene (St), butyl acrylate (BA) in the ‎presence of organic modified montmorillonite (OMMT) with different OMMT contents (0, ‎‎0.5, 1.0, 1.5, and 2.0 wt%). The synthetic compounds are characterized by FTIR, XRD. The ‎nanocomposite emulsions are characterized by applying FTIR, SEM, TEM, TGA and DSC ‎techniques in order to investigate the structure and the thermal properties of the coplymer. ‎The properties of the nanocomposite emulsions containing OMMT are better than styrene-‎acrylate emulsion. The study of monomer conversion versus time and different OMMT ‎contents indicates that the polymerization rate is decreased by increasing the concentration of ‎styrene and OMMT. Consequently the properties of the nanocomposite emulsion containing 1 ‎wt % OMMT are better than other contents. ‎
کلیدواژه‌ها
styrene؛ butyl acrylate, emulsion polymerization؛ nanocomposites؛ montmorillonite ‎
مراجع
[1] G. Xua, C. Denga, L. Xinga, J. Hu, , Int. J. Polymer. Mater., 2013, 62, 488-492.

[2] G. Fei, H. Wang, X. Li, J. Mou, Polym. Bull., 2011, 67, 1017-1028.

[3] B.Q. Jiang, S.F. Hu, J.G. Zou, X.Y. Yu, Appl. Chem. Ind.,  2011, 168-170, 2065-2068.

[4] X.Z. Zhang, P. Wang, L. Liu, J.B. Xiong, Adv. Mater. Res., 2012, 535-537, 2491-2494.

[5] E. Pouget, J. Tonnar, P. Lucas, P. Lacroix-Desmazes, F. Ganachaud, B. Boutevin, Chem. Rev., 2010, 110, 1233-1277.

[6] H. Javaherian Naghash, F. Hajati, J. App. Polym. Sci., 2012, 123, 1227-1237.

[7] B.A. Bhanvase, D.V. Pinjari, P.R. Gogate, S.H. Sonawane, A.B. Pandit, Chem. Eng. J., 2012, 181-182, 770-778.

[8] H. Javaherian Naghash, R. Mohammadrahimpanah, Prog. Org. Coat., 2011, 70, 32-38.

[9] R.P. Moraes, A.M. Santos, P.C. Oliveira, F.C.T. Souza, M.d. Amaral, T.S. Valera, N.R. Demarquette, Macromol. Symp., 2006, 245-246, 106-115.

[10] S.S. Ray, M. Okamoto, Prog. Polym. Sci., 2003, 28, 1539-1641.

[11] J.W. Gilman, W.H. Awad, R.D. Davis, J. Shields, R.H. HarrisJr, C. Davis, A.B. Morgan, T.E. Sutto, J. Callahan, P.C. Trulove, H.C. DeLong, Chem. Mater., 2002, 14, 3776-3785.

[12] M. Zanetti, P. Bracco, L. Costa, Thermal degradation behaviour of PE/clay nanocomposites, Polym. Degrad. Stabil., 2004, 85, 657-665.

[13] J.W. Gilman, Appl. Clay Sci., 1999, 15, 31–49.

[14] A. Leszczynska, J. Njuguna, K. Pielichowski, J.R. Banerjee, ThermochimActa, 2007, 454, 1-22.

[15] E.P. Giannelis, Appl. Organomet. Chem., 1998, 12, 675-680.

[16] Y. Tang, Y. Hu, S. Wang, Z. Gui, Z. Chen, W. Fan, Polym. Degrad. Stabil., 2002, 78, 555-561. 

[17] S. Wang, Y. Hu, R. Zong, Y. Tang, Z. Chen, W. Fan,  Appl. Clay. Sci., 2004, 25, 49-55.

[18] L. Song, Y. Hu, Z. Lin, S. Xuan, S. Wang, Z. Chen, Polym. Degrad. Stabil., 2004, 86, 535-540.

[19] H. Javaherian Naghash, A. Karimzadeh, A.R. Massah, J. Appl. Polym. Sci., 2009, 112, 1037-1044.

[20] X. Yuan, X. Li, E. Zhu, J. Hu, S. Cao, W. Sheng, J. Carbohydr. Polym., 2010, 79, 373-379.

[21] A. Dabbagh, J.L. Ford, M.H. Rubinstein, J.E. Hogan, Int. J.  Pharm., 1996, 140, 85–95.

[22] S. Inukai, T. Tanma, S. Orihara, M. Konno, Chem. Eng. Res. Des., 2001, 79, 901-905.

[23] X. Feng, A. Zhong, D. Chen, J. Appl. Polym. Sci., 2006, 101, 3963-3970.

آمار
تعداد مشاهده مقاله: 1,579
تعداد دریافت فایل اصل مقاله: 990


سامانه مدیریت نشریات علمی. قدرت گرفته از سیناوب