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Mohammadi-Aghdam, Sarvin, Jabbari, Hadi, Pouralimardan, Omidali, Divsar, Fater, Amini, Issa, Sajjadifar, Sami. (1397). One-pot synthesis of highly regioselective β-azido alcohols catalyzed by Brønsted acidic ionic liquids. فصلنامه علمی زیست فناوری گیاهان زراعی, 7(Issue 1, pp. 1-89, Serial No. 22), 15-28. doi: 10.30473/icc.2019.7646
Sarvin Mohammadi-Aghdam; Hadi Jabbari; Omidali Pouralimardan; Fater Divsar; Issa Amini; Sami Sajjadifar. "One-pot synthesis of highly regioselective β-azido alcohols catalyzed by Brønsted acidic ionic liquids". فصلنامه علمی زیست فناوری گیاهان زراعی, 7, Issue 1, pp. 1-89, Serial No. 22, 1397, 15-28. doi: 10.30473/icc.2019.7646
Mohammadi-Aghdam, Sarvin, Jabbari, Hadi, Pouralimardan, Omidali, Divsar, Fater, Amini, Issa, Sajjadifar, Sami. (1397). 'One-pot synthesis of highly regioselective β-azido alcohols catalyzed by Brønsted acidic ionic liquids', فصلنامه علمی زیست فناوری گیاهان زراعی, 7(Issue 1, pp. 1-89, Serial No. 22), pp. 15-28. doi: 10.30473/icc.2019.7646
Mohammadi-Aghdam, Sarvin, Jabbari, Hadi, Pouralimardan, Omidali, Divsar, Fater, Amini, Issa, Sajjadifar, Sami. One-pot synthesis of highly regioselective β-azido alcohols catalyzed by Brønsted acidic ionic liquids. فصلنامه علمی زیست فناوری گیاهان زراعی, 1397; 7(Issue 1, pp. 1-89, Serial No. 22): 15-28. doi: 10.30473/icc.2019.7646

One-pot synthesis of highly regioselective β-azido alcohols catalyzed by Brønsted acidic ionic liquids

Iranian chemical communication
مقاله 2، دوره 7، Issue 1, pp. 1-89, Serial No. 22، فروردین 2019، صفحه 15-28    اصل مقاله (977.75 K)
نوع مقاله: Original Research Article
شناسه دیجیتال (DOI): 10.30473/icc.2019.7646
نویسندگان
Sarvin Mohammadi-Aghdam1؛ Hadi Jabbari2؛ Omidali Pouralimardan2؛ Fater Divsar2؛ Issa Amini2؛ Sami Sajjadifar* 2
1Department of Chemistry, Payame Noor University, PO box 19395-3197, Tehran, Iran
2Department of Chemistry, Payame Noor University, PO BOX 19395-4697 Tehran, Iran
چکیده
In this protocol, 3-(2-carboxybenzoyl)-1-methyl-1H-imidazol-3-ium chloride [Cbmim]Cl and sulfonic acid functionalized pyridinium chloride [pyridine-SO3H]Cl as a new, reusable, and green Brønsted acidic ionic liquid (BAIL) catalyst were synthesized and successfully used for the one-pot ring opening of epoxide with sodium azide (NaN3) in water at room temperature. Epoxides under ring-opening easily with NaN3 in the presence of [Cbmim]Cl and [pyridine-SO3H]Cl to afford the corresponding β-azido alcohols as attractive and interesting materials in drug design and pharmaceutics compounds in high yield with good regioselective under mild reaction conditions.

In this protocol, 3-(2-carboxybenzoyl)-1-methyl-1H-imidazol-3-ium chloride [Cbmim]Cl and sulfonic acid functionalized pyridinium chloride [pyridine-SO3H]Cl as a new, reusable, and green Brønsted acidic ionic liquid (BAIL) catalyst were synthesized and successfully used for the one-pot ring opening of epoxide with sodium azide (NaN3) in water at room temperature. Epoxides under ring-opening easily with NaN3 in the presence of [Cbmim]Cl and [pyridine-SO3H]Cl to afford the corresponding β-azido alcohols as attractive and interesting materials in drug design and pharmaceutics compounds in high yield with good regioselective under mild reaction conditions.
کلیدواژه‌ها
[Cbmim]Cl؛ [pyridine-SO3H]Cl؛ Epoxide؛ Ring opening؛ Azidoalcohols؛ Water
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