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Vahid Fard, Vahid, Shayesteh, Keivan, Abbasi, Pourya, Salimi, Saeid. (1401). Evaluation of Manganometry Method Replacement by Cementation Method to Remove of Cobalt from Zinc Sulfate Solution. فصلنامه علمی زیست فناوری گیاهان زراعی, 9(1), 97-108. doi: 10.30473/ijac.2023.60999.1209
Vahid Vahid Fard; Keivan Shayesteh; Pourya Abbasi; Saeid Salimi. "Evaluation of Manganometry Method Replacement by Cementation Method to Remove of Cobalt from Zinc Sulfate Solution". فصلنامه علمی زیست فناوری گیاهان زراعی, 9, 1, 1401, 97-108. doi: 10.30473/ijac.2023.60999.1209
Vahid Fard, Vahid, Shayesteh, Keivan, Abbasi, Pourya, Salimi, Saeid. (1401). 'Evaluation of Manganometry Method Replacement by Cementation Method to Remove of Cobalt from Zinc Sulfate Solution', فصلنامه علمی زیست فناوری گیاهان زراعی, 9(1), pp. 97-108. doi: 10.30473/ijac.2023.60999.1209
Vahid Fard, Vahid, Shayesteh, Keivan, Abbasi, Pourya, Salimi, Saeid. Evaluation of Manganometry Method Replacement by Cementation Method to Remove of Cobalt from Zinc Sulfate Solution. فصلنامه علمی زیست فناوری گیاهان زراعی, 1401; 9(1): 97-108. doi: 10.30473/ijac.2023.60999.1209

Evaluation of Manganometry Method Replacement by Cementation Method to Remove of Cobalt from Zinc Sulfate Solution

Iranian Journal of Analytical Chemistry
دوره 9، شماره 1 - شماره پیاپی 17، خرداد 2022، صفحه 97-108    اصل مقاله (954.46 K)
نوع مقاله: Full research article
شناسه دیجیتال (DOI): 10.30473/ijac.2023.60999.1209
نویسندگان
Vahid Vahid Fard1؛ Keivan Shayesteh* 1؛ Pourya Abbasi1؛ Saeid Salimi2
1Department of Chemical Engineering, University of Mohaghegh Ardabili, Ardabil, Iran
2Department of Chemical Engineering, Faculty of Engineering, University of Kurdistan, Sanandaj, Iran
چکیده
One of the effective and important steps of the production of Zn in zinc factories is the purification step to remove the general impurities such as cobalt, nickel, and cadmium that can cause the creation of problems in the electrowinning process. In Iran's zinc factories, firstly, at the hot purification step cobalt using the manganometry method, and then at the cold purification step nickel & cadmium using the cementation method with the help of Zn powder removed. In the aim of this study is evaluated the usability of the cementation method instead of the manganometry method. In this paper, important and effective parameters such as temperature, Zn powder dosage, mixing time, amount of trioxide antimony, copper sulfate effect, particle size, zinc ions concentration, mixing speed, and pH of zinc sulfate solution were studied and optimized. The Optimal state is obtained at 85 °C, pH= 4.5, 20 mg/L Sb2O3 concentration, 8 g/L zinc dust, 600 rpm mixing speed in 75 minutes. Decreasing the particle size of zinc dust increased the removal efficiency, but increasing the amounts of copper sulfate and zinc ions caused decreasing in efficiency. Results showed that cobalt, nickel, and cadmium removal efficiencies for the manganomery method were 99%, 0%, and 20% and for the cementation method were 99.5%, 99.7%, and 99.9%, respectively. Also, results indicated that the cementation method due to the increase of soluble zinc concentration; not being removes of manganese ions; simultaneous removal of impurities such as cobalt, nickel, and cadmium in a single step; and saving time and cost, has a higher performance rather than to manganometry method.
کلیدواژه‌ها
Zinc Sulfate Solution؛ Cobalt Removal؛ Manganometry Method؛ Cementation Method؛ Optimization
عنوان مقاله [English]
ارزیابی جایگزینی روش منگانومتری با روش سمنتاسیون برای حذف کبالت از محلول سولفات‌روی
نویسندگان [English]
وحید وحیدفرد1؛ کیوان شایسته1؛ پوریا عباسی1؛ سعید سلیمی2
1دانشکده مهندسی شیمی، دانشگاه محقق اردبیلی، اردبیل، ایران
2دانشکده مهندسی شیمی، دانشگاه کردستان، سنندج، ایران
چکیده [English]
یکی از مراحل موثر و مهم تولید روی در کارخانجات روی، مرحله تصفیه برای حذف ناخالصی ­های متداول مانند کبالت، نیکل و کادمیم است که می ­تواند در فرآیند الکترووینینگ باعث ایجاد مشکل شود. در کارخانجات روی ایران، ابتدا در مرحله تصفیه ­گرم کبالت به­روش منگانومتری و سپس در مرحله تصفیه ­سرد، نیکل و کادمیم به ­روش سیمنتاسیون با کمک پودر روی، حذف می­ شود. هدف از این مطالعه بررسی قابلیت استفاده از روش سمنتاسیون به ­جای روش منگانومتری است. در این مقاله، پارامترهای مهم و موثر مانند مانند دما، مقدار پودر روی، زمان اختلاط، مقدار آنتیموان تری­اکسید، اثر سولفات­مس، اندازه ذرات، غلظت یون روی، سرعت اختلاط و pH محلول سولفات­روی مورد مطالعه و بهینه­ سازی قرار گرفت. حالت بهینه در دمای 85 درجه سانتی­گراد، 4.5=pH، غلظت 20 میلی­گرم در لیتر Sb2O3، 8 گرم در لیتر پودر روی، سرعت اختلاط 600 دور در دقیقه،  در 75 دقیقه به­دست آمد. کاهش اندازه ذرات پودر روی راندمان حذف را افزایش داد؛ اما افزایش غلظت سولفات­مس و یون روی باعث کاهش راندمان شد. نتایج نشان داد که راندمان حذف کبالت، نیکل و کادمیم برای روش منگانومتری به­ترتیب برابر 99، 0، و 20 درصد و برای روش سمنتاسیون به­ترتیب 99.5، 99.7 و 99.9 درصد بود. همچنین نتایج نشان داد که روش سمنتاسیون به ­دلیل افزایش غلظت روی محلول. عدم حذف یون منگنز، حذف همزمان ناخالصی ­هایی مانند کبالت، نیکل و کادمیم در یک مرحله و صرفه ­جویی در زمان و هزینه، عملکرد بهتری نسبت به روش منگانومتری دارد.
کلیدواژه‌ها [English]
محلول سولفات‌روی, حذف کبالت, روش منگانومتری, روش سمنتاسیون, بهینه‌سازی
مراجع
  • Behnajady, and J. Moghaddam, Statistical evaluation and optimization of zinc electrolyte hot purification process by Taguchi method. J. Cent. South Univ. 22(2015) 2066-2072.
  • S. Boyanov, V. V. Konareva, and N. K. Kolev, Purification of zinc sulfate solutions from cobalt and nickel through activated cementation. Hydrometallurgy. 73(2004) 163-168.
  • Behnajady, A. A. Balesini, and J. Moghaddam, A new approach to the optimisation of zinc electrolyte cold purification process by Taguchi’s method. Can. Metall. Q. 53(2014) 333-339.
  • Dib, and L. Makhloufi, Mass transfer correlation of simultaneous removal by cementation of nickel and cobalt from sulfate industrial solution containing copper: Part I: Onto rotating zinc electrode disc. Chem. Eng. J. 130(2006) 39-44.
  • Bae, and K. Yoo, Leaching behavior of valuable metals from by-product generated during purification of zinc electrolyte. Geosystem Eng. 19(2016) 312-316.
  • Zeng, J. P. Zou, Q. Peng, Z. H. Wen, and Y. Xie, Reaction mechanism of cobalt cementation from high cobalt zinc sulfate solution by zinc dust. Can. Metall. Q. 50(2011) 91-93.
  • Friedrich, J. Kruger, and G. Mendez-Bernal, Alternative solution purification in the hydrometallurgical zinc production. Metalurgija, 8(2002) 85-101.
  • Y. Wang, W. H. Gui, K. L. Teo, R. Loxton, and Ch. H. Yang, Optimal control problems arising in the zinc sulfate electrolyte purification process. J. Glob. Optim. 54(2012) 307-323.
  • Xu, K. Ma, and Z. Guo, Activation mechanism of Sb2O3 during removal of cobalt from zinc sulfate solution. Hydrometallurgy. 82(2006) 150-153.
  • Fattahi, F. Rashchia, and E. Abkhoshk, Reductive leaching of zinc, cobalt and manganese from zinc plant residue. Hydrometallurgy. 161(2016) 185-192.
  • Vahidfard, "In study alternative cementation process with using manganometry for removing Cobalt from ZnSO4 solution", M.S. dissertation, University of Mohaghegh Ardabili (2019).
  • Abbasi, K. Shayesteh, V. Vahidfard, and M. Hosseini, Optimization of the nickel removal process from zinc sulfate solution using central composite design of experiments. Iran. J. Anal. Chem. 81(2021) 17-28.
  • Shayesteh, P. Abbasi, V. Vahidfard, and M. Hosseini, Providing practical instruction for solving environmental problems from residue (cake) of cold purification process in zinc production process. J. Environ. Sci. Technol. 23(2021) 53-63.
  • Abbasi, K. Shayesteh, V. Vahidfard, and M. Hosseini, Optimization and comparison of Ni and Cd removal using zinc powder with the response surface methodology. Iran. J. Chem. Eng. 17(2020) 3-20.
  • Güler, and A. Seyrankaya, Precipitation of impurity ions from zinc leach solutions with high iron contents-A special emphasis on cobalt precipitation. Hydrometallurgy, 164(2016 (118-124.
  • Krause, and R. Sandenbergh, Optimization of cobalt removal from an aqueous sulfate zinc leach solution for zinc electrowinning. Hydrometallurgy. 155(2015) 132-140.
  • Zaheri, "High temperature and high pressure cobalt cementation onto zinc dust", M.S. dissertation, University of British Columbia (2015).
  • Dib, and L. Makhloufi, Mass transfer correlation of simultaneous removal by cementation of nickel and cobalt from sulfate industrial solution containing copper: Part II: Onto zinc powder. Chem. Eng. J. 123(2007) 53-58.
  • Casaroli, B. Cohen, A. R. Tong, and P. Linkson, Cementation for metal removal in zinc electrowinning circuits. Miner. Eng. 18(2005) 1282-1288.
  • Boyanov, V. Konareva, and N. Kolev, Removal of cobalt and nickel from zinc sulfate solutions using activated cementation. J. Min. Metall. B. 40(2004) 41-55.
  • B. Kayin, "Removal of cobalt from zinc sulfate solution by cementation prior to zinc electrowinning", M.S. dissertation, Middle East Technical University (2003).
  • Bøckman, T. Østvold, G. A. Voyiatzis, and G. N. Papatheodorou, Raman spectroscopy of cemented cobalt on zinc substrates. Hydrometallurgy. 55(1) (2000) 93-105.
  • Raghavan, P. K. Mohanan, and S. K. Verma, Modified zinc sulfate solution purification technique to obtain low levels of cobalt for the zinc electrowinning process. Hydrometallurgy, 51(1999) 187-206.
  • Nelson, "Novel activators in cobalt removal from zinc electrolyte by cementation", M.S. dissertation, McGill University Montreal PQ (1999).
  • Lu, D. B. Dreisinger, and W. C. Cooper, Cobalt precipitation by reduction with sodium borohydride. Hydrometallurgy. 45(1997) 305-322.
  • Singh, Technological innovation in the zinc electrolyte purification process of a hydrometallurgical zinc plant through reduction in zinc dust consumption. Hydrometallurgy. 40(1996) 247-262.
  • M. Polcaro, S. Palmas, and S. Dernini, Kinetics of cobalt cementation on zinc powder. Ind. Eng. Chem. Res. 34(1995) 3090-3095.
  • Van Der Pas, "A fundamental study of cobalt cementation with zinc dust in the presence of copper and antimony additives", M.S. dissertation, University of British Columbia (1995).
  • W. Lew, "The removal of cobalt from zinc sulfate electrolytes using the copper-antimoney process", M.S. dissertation, University of British Columbia (1994).
  • Tozawa, T. Nishimura, M. Akahori, and M. A. Malaga, Comparison between purification processes for zinc leach solutions with arsenic and antimony trioxides. Hydrometallurgy. 30(1992) 445-461.
  • S. Blaser, and T. J. O’Keefe, Screening design test for cobalt cementation from zinc electrolyte. Metall. Mater. Trans. B. 14(1983) 495-497.
  • Nelson, W. Wang, G. P. Demopoulos, and G. Houlachi, The removal of cobalt from zinc electrolyte by cementation: a critical review. Miner. Process. Extr. Metall. Rev. 20(2000) 325-356.
  • J. Krause, "Optimisation of the purification process of a zinc sulfate leach solution for zinc electrowinning", M.S. dissertation, University of Pretoria (2014).
  • Yang, G. Xie, G. Zeng, J. Wang, and R. Li, Mechanism of cobalt removal from zinc sulfate solutions in the presence of cadmium. Hydrometallurgy. 81(2006) 62-66.
  • Zeng, G. Xie, D. Yang, J. Wang, X. Li, and R. Li, The effect of cadmium ion on cobalt removal from zinc sulfate solution. Miner. Eng. 19(2006) 197-200.
  • Shayesteh, P. Abbasi, V. Vahidfard, and M. Shahedi Asl, Simultaneous removal of nickel and cadmium during the cold purification of zinc sulfate solution. Arab. J. Sci. Eng. 45(2020) 587-598.
  • Vahidfard, K. Shayesteh, P. Abbasi, and M. Hosseini, Analysis of effective parameters on cadmium cementation reaction from the perspective of diffusion. Journal of Particle Science & Technology. 6(2021) 81-93.
  • Hosseini, K. Shayesteh, V. Vahidfard, and P. Abbasi, Feasibility of zinc recovery from hot-filtrate cake (waste) as practical approach to resolve of environmental problems in zinc industry. J. Environ. Sci. Technol. In press.
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