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Karim-Nezhad, Ghasem, Pashazadeh, Sara, Honarmand, Samira. (1400). Study on Electrochemical Behavior of Hydrazine at a Glassy Carbon Electrode Modified with Polymer Thin Films Embedded Copper Nanoparticles. فصلنامه علمی زیست فناوری گیاهان زراعی, 8(2), 40-49. doi: 10.30473/ijac.2022.62498.1214
Ghasem Karim-Nezhad; Sara Pashazadeh; Samira Honarmand. "Study on Electrochemical Behavior of Hydrazine at a Glassy Carbon Electrode Modified with Polymer Thin Films Embedded Copper Nanoparticles". فصلنامه علمی زیست فناوری گیاهان زراعی, 8, 2, 1400, 40-49. doi: 10.30473/ijac.2022.62498.1214
Karim-Nezhad, Ghasem, Pashazadeh, Sara, Honarmand, Samira. (1400). 'Study on Electrochemical Behavior of Hydrazine at a Glassy Carbon Electrode Modified with Polymer Thin Films Embedded Copper Nanoparticles', فصلنامه علمی زیست فناوری گیاهان زراعی, 8(2), pp. 40-49. doi: 10.30473/ijac.2022.62498.1214
Karim-Nezhad, Ghasem, Pashazadeh, Sara, Honarmand, Samira. Study on Electrochemical Behavior of Hydrazine at a Glassy Carbon Electrode Modified with Polymer Thin Films Embedded Copper Nanoparticles. فصلنامه علمی زیست فناوری گیاهان زراعی, 1400; 8(2): 40-49. doi: 10.30473/ijac.2022.62498.1214

Study on Electrochemical Behavior of Hydrazine at a Glassy Carbon Electrode Modified with Polymer Thin Films Embedded Copper Nanoparticles

Iranian Journal of Analytical Chemistry
مقاله 6، دوره 8، شماره 2 - شماره پیاپی 16، آذر 2021، صفحه 40-49    اصل مقاله (1.22 M)
نوع مقاله: Full research article
شناسه دیجیتال (DOI): 10.30473/ijac.2022.62498.1214
نویسندگان
Ghasem Karim-Nezhad* 1؛ Sara Pashazadeh2؛ Samira Honarmand1
1Department of Chemistry, Payame Noor University, PO BOX 19395-3697, Tehran, Iran
2Electroanalytical Chemistry Laboratory, Department of Chemistry, Faculty of Sciences, Azarbaijan Shahid Madani University, Tabriz 53714-161, Iran
چکیده
In this study, a novel and convenient electrochemical sensor was fabricated by using dripping well-dispersed graphene oxide nanosheets, electropolymerization of poly glycine (p-Gly) and in situ plating of metallic copper nanoparticle film methods, successively. This sensor was further employed to investigate the electrochemical behavior of hydrazine. Scanning electron microscopy and energy dispersive X-ray spectrometry were used for the characterization of the prepared film. Anodic peak potential of hydrazine oxidation at the surface of modified electrode shifts by about 150 mV toward negative values compared with that on the bare electrode. The kinetic parameters such as the electron transfer coefficient (α) and charge transfer rate constant (k) for the oxidation of hydrazine was determined utilizing cyclic voltammetry (CV). The diffusion coefficient (D) of hydrazine was also estimated using chronoamperometry. The dynamic detection range of this sensor to hydrazine was 5- 60 and 80- 150 µM at the modified electrode surface using an amperometric method. The detection limit and quantitation are 5.33 µM and 17.77 µM, respectively. A new voltammetric method for determination of hydrazine was erected and shows good sensitivity and selectivity, wider linear relationship, very easy surface update and good stability.
کلیدواژه‌ها
Hydrazine؛ Modified Glassy Carbon Electrode؛ Copper Nanoparticle؛ Glycine. Graphene Oxide Nanosheets
عنوان مقاله [English]
مطالعه رفتار الکتروشیمیایی هیدرازین در سطح الکترود کربن شیشه ای اصلاح شده با لایه های نازک پلیمری دوپه شده با نانوذرات مس
نویسندگان [English]
قاسم کریم نژاد1؛ سارا پاشا زاده2؛ سمیرا هنرمند1
1گروه شیمی، دانشگاه پیام نور، صندوق پستی 4697- 19395، تهران، ایران
2گروه شیمی، دانشکده علوم، دانشگاه شهید مدنی آذربایجان، تبریز 53714-161، ایران
چکیده [English]
 
در این مطالعه، یک حسگر الکتروشیمیایی جدید با استفاده از نانو ورقه‌های گرافن اکسید ، الکتروپلیمریزاسیون پلی گلیسین و سنتز در محل فیلم نانوذرات مس تهیه شد. این سنسور برای بررسی رفتار الکتروشیمیایی هیدرازین استفاده شد. از میکروسکوپ الکترونی روبشی و طیف سنجی پراش اشعه ایکس برای بیان ویژگی های فیلم تهیه شده استفاده شد. در مقایسه با الکترود اصلاح نشده، پتانسیل پیک آندی اکسیداسیون هیدرازین در سطح الکترود اصلاح شده حدود 150 میلی ولت به سمت مقادیر منفی جابجا می شود. پارامترهای سینتیکی از قبیل ضریب انتقال الکترون (α) و ثابت سرعت انتقال بار (k) برای اکسیداسیون هیدرازین با استفاده از ولتامتری چرخه ای تعیین شد. ضریب انتشار (D) هیدرازین نیز با استفاده از روش کرونوآمپرومتری محاسبه شد. محدوده تشخیص دینامیکی این حسگر نسبت به هیدرازین در سطح الکترود اصلاح شده با استفاده از روش آمپرومتری در محدوده 60-5 و 150-80 میکرومولار می باشد و حد تشخیص روش حدود 33/5 میکرومولار به دست آمد. یک روش ولتامتری جدید برای اندازه گیری هیدرازین ایجاد شد که حساسیت و گزینش پذیری خوب و محدوده خطی گسترده تری را نشان می دهد.
کلیدواژه‌ها [English]
هیدرازین, الکترود کربن شیشه ای اصلاح شده, نانو ذره مس, گلیسین, نانو ورقه های گرافن اکسید
مراجع
  • S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, Y. Zhang, S.V. Dubonos, I.V. Grigorieva and A.A. Firsov, Electric field effect in atomically thin carbon films, Science, 306 (2004) 666–669.
  • Stankovich, D.A. Dikin, G.H.B. Dommett, K.M. Kohlhaas, E.J. Zimney, E.A.  Stach, R.D. Piner, S.T.Nguyen, R.S. Ruoff, Graphene based-composite materials, Nature, 442 (2006) 282–286.
  • S. Bunch, A.M. van der Zande, S.S. Verbridge, I.W. Frank, D.M. Tanenbaum, J.M. Parpia, H.G. Craighead, P.L. McEuen, Electromechanical resonators from graphene sheets, Science, 315 (2007) 490–493.
  • Deng, M. Zhu, T. Jin, C. Cheng, J. Zheng, Y. Qian, One-step synthesis of nitrogen, sulphur-codoped graphene as electrode material for supercapacitor with excellent cycling stability, Int. J. Electrochem. Sci. 15 (2020) 16–25.
  • Liu, C.K. Poh, D. Zhan, L. Lai, S.H. Lim, L. Wang, X. Liu, N.G. Sahoo, C. Li, Z. Shen, Improved synthesis of grapheneflakes from the multiple electrochemical exfoliation of graphite rod, Nano Eng. 2 (3) (2013) 377–386.
  • Fan, Y. Xu, T. Sheng, D. Zhao, H. Yuan, F. Liu, X. Liu, X. Zhu, L. Zhang, J. Lu, Amperometric sensor for dopamine based on surface-graphenization pencil graphite electrode prepared by in-situ electrochemical delamination, Microchim. Acta 186 (5) (2019) 324.
  • -H. Chen, S.-W. Yang, M.-C. Chuang, W.-Y. Woon, C.-Y. Su, Towards the continuous production of high crystallinity graphene via electrochemical exfoliation with molecular in situ encapsulation, Nanoscale 7 (37) (2015) 15362–15373.
  • Vasseghian, D. Elena-Niculina, M. Moradi, and A. Mousavi Khaneghah. A review on graphene-based electrochemical sensor for mycotoxins detection, Food and Chemical Toxicology 148 (2021) 111931.
  • Gupta, C. N. Murthy, and C. R. Prabha. Recent advances in carbon nanotube based electrochemical biosensors. International journal of biological macromolecules 108 (2018) 687-703.
  • Song, Z. Xiaoyuan, L. Yunfang, and S. Zhiqiang. Developing Graphene‐Based Nanohybrids for Electrochemical Sensing, The Chemical Record 19 (2019) 534-549.
  • Lakra, R. Kumar, P. K. Sahoo, D. Thatoi, and A. Soam. A mini-review: Graphene based composites for supercapacitor application, Inorganic Chemistry Communications 133 (2021) 108929.
  • I. Bolotin, K.J. Sikes, Z. Jiang, M. Klima, G. Fudenberg, J. Hone, P. Kim, H.L. Stormer, Ultrahigh electron mobility in suspended graphene, Solid State munications, 146 (2008) 351–355.
  • A. Balandin, S. Ghosh, W. Bao, I. Calizo, D. Teweldebrhan, F. Miao, C.N. Lau, Superior thermal conductivity of single-layer graphene, Nano Letters, 8(2008) 902–907.
  • Beitollai, S. Mohadeseh, and S. Tajik. "Application of Graphene and Graphene Oxide for modification of electrochemical sensors and biosensors: A review." Int. J. Nano Dim. 10, no. 2 (2019): 125-140.
  • Kumar, N. Venkatesh, H. Bhowmik, & A. Kuila, Metallic nanoparticle: a review. Biomed. J. Sci. & Tech. Rese.4(2) (2018) 3765-3775.
  • Wu, Z. Jianhua, and H. Lu, A review of three-dimensional graphene-based materials: Synthesis and applications to energy conversion/storage and environment, Carbon 143 (2019) 610-640.
  • Zhao, W. Zhenhui, Q. Li, Fabrication of a nichrome electrode coated with silver microcrystals, and its application to sensing hydrogen peroxide, Anal. Methods, 4(2012) 1105-1109.
  • C. Pereira, M.V.B. Zanoni, Voltammetric sensor for sodium nitroprusside determination in biological fluids using films of poly-L-lysine, Electroanalysis, 19 (2007( 993– 998.
  • -B. Raoof, R. Ojani, and S. Rashid-Nadimi, Preparation of polypyrrole/ferrocyanide films modified carbon paste electrode and its application on the electrocatalytic determination of ascorbic acid, Electrochim. Acta., 49(2004) 271–280.
  • Y Huang, F Bao, M Ji, Y Hu, L Huang, H Liu, J. Yu, G. Cong, C. Zhu, and J. Xu. A polyaniline-modified electrode surface for boosting the electrocatalysis towards the hydrogen evolution reaction and ethanol oxidation reaction, Chem. Commun. 57, no. 100 (2021) 13792-13795.
  • V. de Melo, M.E. Bello, W.M. de Azevêdo, J.M. de Souza, F.B. Diniz, The effect of glutaraldehyde on the electrochemical behavior of polyaniline, Electrochim. Acta., 44 (1999) 2405–2412.
  • Zhang, Z. Wang, Y. Zhang, Z. Zheng, C. Wang, Y. Du, W. Ye, Simultaneous electrochemical determination of uric acid, xanthine and hypoxanthine based on poly(l-arginine)/graphene composite film modified electrode, Talanta, 93 (2012) 320–325.
  • Liu, L. Luo, Y. Ding, D. Ye, Poly-glutamic acid modified carbon nanotube-doped carbon paste electrode for sensitive detection of L-tryptophan, Bioelectrochemistry, 82 (2011) 38–45.
  • Saeb, K. Asadpour-Zeynali, Facile synthesis of TiO2@ PANI@ Au nanocomposite as an electrochemical sensor for determination of hydrazine, Microchem. J. 160 (2021) 105603.
  • Wang, J. Ding, P. Kannan, S. Ji, Cobalt nanoparticles intercalated nitrogen-doped mesoporous carbon nanosheet network as potential catalyst for electro-oxidation of hydrazine, Int. J. Hydrog. Energy. 45 (38) (2020) 19344-19356.
  • S. Hummers Jr, R.E. Offeman, Preparation of graphitic oxide, J. Am. Chem. Soc., 80 (1958) 1339–1339.
  • J. Bard, L.R. Faulkner, Electrochemical Methods, Fundamentals and Applications, Wiley, New York, 1980.
  • Chong, Z. Mei, L. Shanshan, G. Xinlei, W. Wei, H. Guanghui, Determination of hydrazine in prednisolone by derivatization-gas chromatography-triple quadrupole mass spectrometry, Chin. J. Chromatogr. 39 (7) (2021) 750.
  • Habibi, S. Pashazadeh, L.A. Saghatforoush and A. Pashazadeh. "Direct electrochemical synthesis of the copper based metal-organic framework on/in the heteroatoms doped graphene/pencil graphite electrode: Highly sensitive and selective electrochemical sensor for sertraline hydrochloride." J. Electroanal. Chem.888 (2021) 115210-115222.
  • Habibi, S. Pashazadeh, L. A. Saghatforoush, and A. Pashazadeh, A thioridazine hydrochloride electrochemical sensor based on zeolitic imidazolate framework-67-functionalized bio-mobile crystalline material-41 carbon quantum dots. New J. Chem. 45 (32) ( 2021) 14739-50.
  • Karim-Nezhad, R. Jafarloo, P. Seyed Dorraji, Copper (hydr) oxide modified copper electrode for electrocatalytic oxidation of hydrazine in alkaline media, Electrochim. Acta., 54 )2009( 5721– 5726.
  • D.D.C. Conceicao, R.C. Faria, O. Fatibello-Filho, A.A. Tanaka, Electrocatalytic oxidation and voltammetric determination of hydrazine in industrial boiler feed water using a cobalt phthalocyanine-modified electrode, Anal. Lett. 41 (2008) 1010–1021.
  • R. Majidi, A. Jouyban, K. Asadpour-Zeynali, Electrocatalytic oxidation of hydrazine at overoxidized polypyrrole film modified glassy carbon electrode, J. electrochim. Acta., 52 ( 2007) 6248–6253.
  • Abbaspour, A. Khajehzadeh, A. Ghaffarinejad, Electrocatalytic oxidation and determination of hydrazine on nickel hexacyanoferrate nanoparticles-modified carbon ceramic electrode, J. Electroanal.Chem., 631 (2009) 52–57.
  • Nasirizadeh, H.R. Zare, A.R. Fakhari, H. Ahmar, M.R. Ahmadzadeh, A. Naeimi, A study of the electrochemical behavior of an oxadiazole derivative electrodeposited on multi-wall carbon nanotube-modified electrode and its application as a hydrazine sensor, J. Solid State Electrochem., 15 (2011) 2683–2693.
  • Zhang, J. Huang, H. Hou, T. You, Electrochemical detection of hydrazine based on electrospun palladium nanoparticle/carbon nanofibers, Electroanalysis, 21 (2009) 1869–1874.
  • Ji, C.E. Banks, A.F. Holloway, K. Jurkschat, C.A. Thorogood, G.G. Wildgoose, R.G. Compton, Palladium Sub-Nanoparticle Decorated ‘Bamboo’ Multi-Walled Carbon Nanotubes Exhibit Electrochemical Metastability: Voltammetric Sensing in Otherwise Inaccessible pH Ranges, Electroanalysis, 18 (2006) 2481–2485.
  • A. Ensafi, E. Mirmomtaz, Electrocatalytic oxidation of hydrazine with pyrogallol red as a mediator on glassy carbon electrode, J. Electroanal.Chem., 583 (2005) 176–183.
  • Ahmar, S. Keshipour, H. Hosseini, A.R. Fakhari, A. Shaabani, A. Bagheri, Electrocatalytic oxidation of hydrazine at glassy carbon electrode modified with ethylenediamine cellulose immobilized palladium nanoparticles, J. Electroanal. Chem., 690(2013) 96–103.
  • Karim-Nezhad, L. Samandari, Thiourea Modified Copper Electrode: Application to Electrocatalytic Oxidation of Hydrazine, Anal. Bioanal. Electrochem, 6 (2014) 545-558.
  • Yi and W. g. Yu, Nanoporous gold particles modified titanium electrode for hydrazine oxidation, J. Electroanal. Chem., 633 (2009) 159–164.
  • Afzali, H.K. Maleh, M.A. Khalilzadeh, Sensitive and selective determination of phenylhydrazine in the presence of hydrazine at a ferrocene-modified carbon nanotube paste electrode, Environ. Chem. Lett., 9 (2011) 375–381.
  • Rani, M. Kumar, Amperometric Determination of Hydrazine Based on Copper Oxide Modified Screen Printed Electrode, Sensors & Transducers. 223 (7) (2018) 22-25.
  • Ning, X. Guan, J. Ma, M. Wang, X. Fan, G. Zhang, F. Zhang, W. Peng, Y. Li, A highly sensitive nonenzymatic H2O2 sensor based on platinum, ZnFe2O4 functionalized reduced graphene oxide, J. Alloys Compd. 738 (2018) 317-322.
  • Zhou, P. Lu, Z. Zhang, Q. Wang, A. Umar, Perforated Co3O4 nanoneedles assembled in chrysanthemum-like Co3O4 structures for ultra-high sensitive hydrazine chemical sensor, Sens. Actuators B Chem. 235 (2016) 457-465.
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