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Monsef Khoshhesab, Zahra, Mohammadi Pour Salehloo, Mohammadreza. (1400). Adsorptive Removal of Reactive Blue 25 and Reactive Blue 49 Dyes from Aquatic Solutions Using Zinc Oxide Nanoparticles. فصلنامه علمی زیست فناوری گیاهان زراعی, 8(2), 59-68. doi: 10.30473/ijac.2022.62547.1220
Zahra Monsef Khoshhesab; Mohammadreza Mohammadi Pour Salehloo. "Adsorptive Removal of Reactive Blue 25 and Reactive Blue 49 Dyes from Aquatic Solutions Using Zinc Oxide Nanoparticles". فصلنامه علمی زیست فناوری گیاهان زراعی, 8, 2, 1400, 59-68. doi: 10.30473/ijac.2022.62547.1220
Monsef Khoshhesab, Zahra, Mohammadi Pour Salehloo, Mohammadreza. (1400). 'Adsorptive Removal of Reactive Blue 25 and Reactive Blue 49 Dyes from Aquatic Solutions Using Zinc Oxide Nanoparticles', فصلنامه علمی زیست فناوری گیاهان زراعی, 8(2), pp. 59-68. doi: 10.30473/ijac.2022.62547.1220
Monsef Khoshhesab, Zahra, Mohammadi Pour Salehloo, Mohammadreza. Adsorptive Removal of Reactive Blue 25 and Reactive Blue 49 Dyes from Aquatic Solutions Using Zinc Oxide Nanoparticles. فصلنامه علمی زیست فناوری گیاهان زراعی, 1400; 8(2): 59-68. doi: 10.30473/ijac.2022.62547.1220

Adsorptive Removal of Reactive Blue 25 and Reactive Blue 49 Dyes from Aquatic Solutions Using Zinc Oxide Nanoparticles

Iranian Journal of Analytical Chemistry
مقاله 8، دوره 8، شماره 2 - شماره پیاپی 16، آذر 2021، صفحه 59-68    اصل مقاله (939.3 K)
نوع مقاله: Full research article
شناسه دیجیتال (DOI): 10.30473/ijac.2022.62547.1220
نویسندگان
Zahra Monsef Khoshhesab* ؛ Mohammadreza Mohammadi Pour Salehloo
Department of Chemistry, Payame Noor University, 19395-4697, Tehran, Iran
چکیده
In this work, Zinc oxide nanoparticles (ZnONPs) were utilized as a potential adsorbent for the adsorption of Reactive Blue 25 (RB25) and Reactive Blue 49 (RB49) dyes from aqueous solutions. ZnONPs adsorbent was synthesized by precipitation method and characterized using XRD, TEM, SEM, and N2 adsorption /desorption techniques. The effect of various parameters including solution pH, shaking time, adsorbent amount and initial concentration of the dyes on the adsorption efficiency was studied. The experimental adsorption data analyzed with various kinetic and isothermal methods. The adsorption kinetic study revealed that the adsorption process followed pseudo-second-order kinetic model. Additionally, adsorption isotherm studies indicated that adsorption equilibrium data were well fitted to Langmuir model and accordingly, the maximum adsorption capacity of the adsorbent for RB25 and RB49 found to be 34.36 and 34.60 (mg/g), respectively. From this study, ZnONPs is suggested as an effectual adsorbent for the removal of dyes from aqueous samples.
کلیدواژه‌ها
Reactive Blue 25؛ ZnO Nanoparticles؛ Reactive Blue 49؛ Dye Removal؛ Water Treatment
عنوان مقاله [English]
حذف رنگ های راکتیوآبی25 و راکتیو آبی 49 از محلول های آبی با استفاده از نانوذرات روی اکسید
نویسندگان [English]
زهرا منصف خوشحساب؛ محمدرضا محمدی پور صالح لو
گروه شیمی، دانشکده علوم، دانشگاه پیام نور، تهران، ایران
چکیده [English]
 
در این کار ، نانوذرات روی اکسید به عنوان جاذب برای جذب رنگ های ری اکتیو آبی 25 و ری اکتیو آبی 49 از محلول­های آبی مورد استفاده قرار گرفت.  نانو ذرات روی اکسید با روش رسوبی سنتز و با استفاده از فنون SEM،TEM ، XRD و جذب و واجذبی نیتروژن مشخصه یابی شدند. اثر عوامل مختلف مانند pH محلول، زمان شیکر، مقدار جاذ ب و غلظت اولیه رنگ بر کارایی جذب مورد بررسی قرار گرفت. داده­های تجربی با مدل های سینیتیکی و همدماهای جذبی مختلف ارزیابی شدند. نتایج بدست آمده تبعیت سینیتیک جذب از مدل سینیتیکی شبه مرتبه دوم را نشان داد. همچنین، مطالعه همدماهای جذب حاکی از انطباق داده های جذبی با همدمای لانگ مویر است و بر این اساس، بیشترین ظرفیت جذب برای رنگ رای کتیو آبی 25 و ری اکتیو آبی 49 بترتیب 34.36و 34.60 تعیین شد. با توجه به نتایج  این تحقیق، نانوذرات روی اکسید به عنوان یک جاذب موثر و کارامد برای حذف رنگ ها از نمونه های آبی پیشنهاد شدند.
کلیدواژه‌ها [English]
ری اکتیو آبی 49, ری اکتیو آبی 25, ناوذرات روی, حذف رنگ, تصفیه آب
مراجع
  • El-khomri, N. El-messaoudi, S. Bentahar, A. Dbik and A. Lacherai, Removal of Cationic Dye from Aqueous Solution using Agricultural Wastes: Argan and Almond Shells, Iran. J. Energ. Environ. 9(4) (2018) 255- 262.
  • Sivalingam, S , Sen Efficient removal of textile dye using nanosized fly ash derived zeolite-x: Kinetics and process optimization study, J. Taiwan Inst. Chem. Eng. 96 (2019) 305-314.
  • Huang, M. Yan, K. He, Z. Huang, G. Zeng, A. Chen, M. Peng, L. Yuan and G. Chen, Efficient removal of methylene blue from aqueous solutions using magnetic graphene oxide modified zeolite, J. Colloid Interface Sci. 543 ( 2019) 43-51.
  • Abdi, N.M. Mahmoodi, M. Vossoughi and I. Alemzadeh, Synthesis of magnetic metalorganic framework nanocomposite (ZIF-8@SiO2@MnFe2O4) as a novel adsorbent for selective dye removal from multicomponent systems, Microporous Mesoporous Mater. 273 (2019) 177–188.
  • Wang, H. Gao, M. Chen, X. Xu, X. Wang, C. Pan and J. Gao, Microwave-assisted synthesis of reduced graphene oxide/titania nanocomposites as an adsorbent for methylene blue adsorption, Appl. Surf. Sci. 360 (2016) 840–848.
  • EL Khomri, EL. Lacherai, and N. Messaoudi, Retention of Methylene Blue on an Agro-Source Material. International, Eng. Res. Tech. 3 (2014)1657–1662.
  • Agrawal, D. Tipre, B. Patel and S. Dave, Optimization of triazo Acid Black 210 dye degradation by Providencia sp. SRS82 and elucidation of degradation pathway, Process Biochem. 49 (2014) 110-119.
  • Pandimurugan and S. Thambidurai, Synthesis of seaweed-ZnO-PANI hybrid composite for adsorption of methylene blue dye, J. Environ. Chem. Eng. 4 (2016) 1332–1347.
  • A. Pavan, E. S. Camacho, E. C. Lima, G. L. Dotto, V. T. Branco and S. L. Dias, Formosa papaya seed powder (FPSP): preparation, characterization and application as an alternative adsorbent for the removal of crystal violet from aqueous phase, J. Environ. Chem. Eng. 2 (2014) 230-238.
  • Li, D.H.L.Ngb, P. Songa, C.K. Konga and Y. Song, Synthesis of SnO2-activated carbon fiber hybrid catalyst for the removal of methyl violet from water, Mater. Sci. Eng. B, 194 (2015) 1-8.
  • Siddique, R. Farooq and A. Shaheen, Removal of Reactive Blue 19 from Wastewaters by Physicochemical and Biological Processes- A Review, J. Chem. Soc. Pak. 33 (2011) 284-293.
  • Rafatullah, O. Sulaiman, R. Hashim and A. Ahmad, Adsorption of methylene blue on low-cost adsorbents: A review, J. Hazard. Mater. 177 (2010) 70 - 80.
  • Monsef Khoshhesab, K. Gonbadi and Gh. Rezaei Behbehani, Removal of reactive black 8 dye from aqueous solutions using zinc oxide nanoparticles: investigation of adsorption parameters, Desalin. Water Treat. 56 (2015) 1558-1565.
  • Isanejad, M. Arzani, H.R. Mahdavi and T. Mohammadi, Novel amine modification of ZIF-8 for improving simultaneous removal of cationic dyes from aqueous solutions using supported liquid membrane, J. Mol. Liq. 225 (2017) 800–809.
  • Ayazi, Z. Monsef Khoshhesab, F. F. Azhar and Z. Mohajeri, modeling and Optimization of Adsorption Removal of Reactive Orange 13 on the Alginate–Montmorillonite–Polyaniline Nanocomposite via Response Surface Methodology, J. Chin. Chem. Soc. 64 (2017) 627-639.
  • Balasubramani, N. Sivarajasekar and M. Naushad, Effective adsorption of antidiabetic pharmaceutical (metformin) from aqueous medium using graphene oxide nanoparticles: equilibrium and statistical modelling, J. Mol. Liq. 301 (2020) 112–426.
  • Monsef khoshhesab and M. Ahmadi, Removal of reactive blue 19 from aqueous solutions using NiO nanoparticles: equilibrium and kinetic studies, Desalin. Water Treat. 57 (2016) 20037-20048.
  • Sun, M. Chen, H. Liu, Y. Zhu, D. Wang and M. Yan, Adsorptive removal of dye and antibiotic from water with functionalized zirconium-based metal organic framework and graphene oxide composite nanomaterial Uio-66-(OH)2/GO, Appl. Surf. Sci. 525 (2020)146614-146621.
  • R.Bonetto, F.Ferrarini, C.de Marco, J.S.Crespo, R.Guégan and M.Giovanela, Removal of methyl violet 2B dye from aqueous solution using a magnetic composite as an adsorbent, J. Water Process Eng. 6 (2015)11-20.
  • A. Narvekar, J.B, Fernandes and S.G. Tilve, Adsorption behavior of methylene blue on glycerol -based carbon materials, J. Environ. Chem. Eng. 6 (2018)1714-1725.
  • Li, R. Yang, M. Yu, F. Bai, C. Li and Z.L. Wang, Cellular Level Biocompatibility and Biosafety of ZnO Nanowires, J. Phys. Chem. C, 112 (2008), 20115-20117.
  • Gopikrishnan, K. Zhang, P. Ravichandran, S. Baluchamy, V. Ramesh, S. Biradar, P. Ramesh, J. Pradhan, J. Hall, A.K. Pradhan and G.T. Ramesh, Synthesis, characterization and biocompatibility studies of zinc oxide (ZnO) nanorods for biomedical application, Nano-Micro Lett. 2 (2010) 31-36.
  • Monsef Khoshhesab and S. Souhani, Adsorptive removal of reactive dyes from aqueous solutions using zinc oxide nanoparticles, J. Chin. Chem. Soc. 52(2018)1482-1490.
  • A. Sahbaz, S. Dandil and C. Acigoz, Studies on the Removal of Reactive Blue 49 Dye from Aqueous Solution onto Chitosan-Activated Sludge Composite Particles, Bio. Chem. Res. 6 (2019) 19-29.
  • Jarusiripot, Removal of Reactive Dye by Adsorption over Chemical Pretreatment Coal Based Bottom Ash, Procedia Chem. 9 (2014) 121- 130.
  • Sangjan, M. Sratongin, A. Kawpakpor, P. Ampha, L. Jamtanom and K. Kaewbang, Activated Carbon as Heterogeneous Catalyst of Catalytic Ozonation Activity for Improvement RB 49 Dye Degradation, Mater. Sci. Forum 860 (2016) 105-110.
  • Monsef Khoshhesab, M. Sarfaraz and M. AsadiAsadabad, Preparation of ZnO nanostructures by chemical precipitation method, Synth. React. Inorg. Met.-Org. Nano-Met. Chem. 41 (2011) 814 -819.
  • Qin, M. Long, B. Tan and B. Zhou, RhB adsorption performance of magnetic adsorbent Fe3O4/RGO composite and its regeneration through A fenton-like reaction, Nano-Micro Lett. 6 (2014)125- 135.
  • Noei , H. Qui, Y. Wang, E. Loffler and C. Woll, The identification of hydroxyl groups on ZnO nanoparticles by infrared spectroscopy, Phys. Chem. Chem. Phys. 10 (2008) 7092 -7097.
  • A. Park, The Isoelectric points of solid oxides, solid hydroxides, and aqueous hydroxo complex systems, Chem. Rev. 65 (1965) 177-198.
  • Daneshvar, N.S. Aber, M.S. Seyed Dorraji, A.R. Khataee and M.H. Rasoulifard, Photocatalytic degradation of the insecticide diazinon in the presence of prepared nanocrystalline ZnO powders under irradiation of UV-C light, Sep. Pur. Technol. 58 (2007) 91-98.
  • -S. Ho and G. McKay, Pseudo-second order model for sorption processes, Process Biochem. 34 (1999) 451-465.
  • Largergren, About the theory of so-called adsorption of soluble substances. K. Sven, Veten, Hand, Handlingar, 24 (1898) 1-39.
  • Vadivelan, K.V. Kumar, Equilibrium, kinetics, mechanism, and process design for the sorption of methylene blue onto rice husk, J. Colloid Interface Sci. 286 (2005) 90-100.
  • C. Lai, L.Y. Lee, B.Y.Z. Hiew, T.C.-K Yang, G.-T. Pan, S. Thangalazhy-Gopakumar, S. Gan, Utilisation of eco-friendly and low-cost 3D graphene-based composite for treatment of aqueous Reactive Black 5 dye: Characterisation, adsorption mechanism and recyclability studies, J. Taiwan Inst. Chem. Eng. 114 (2020) 57–66.
  • Langmuir, I. The adsorption of gases on plane surfaces of glass, mica and platinum, J. Am. Chem. Soc. 40 (1918) 1361-1403.
  • Freundlich, Over the adsorption in solution, J. Phys. Chem. 57 (1906) 385- 471.
  • Hall, L.C. Eagleton, A. Acrivos and T. Vermeulen, Pore and solid diffusion kinetics in fixed-bed adsorption under constant pattern conditions, Ind. Eng. Chem. Fundam. 5 (1996) 212–223.
 

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